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The water vapor transport associated with latent heat flux (LE) in the planetary boundary layer (PBL) is critical for the atmospheric hydrological cycle, radiation balance, and cloud formation. The spatiotemporal variability of LE and water vapor mixing ratio (r_v) are poorly understood due to the scale‐dependent and nonlinear atmospheric transport responses to land surface heterogeneity. Here, airborne in situ measurements with the wavelet technique are utilized to investigate scale‐dependent relationships among LE, vertical velocity (w) variance (), andr_vvariance () over a heterogeneous surface during the Chequamegon Heterogeneous Ecosystem Energy‐balance Study Enabled by a High‐density Extensive Array of Detectors 2019 (CHEESEHEAD19) field campaign. Our findings reveal distinct scale distributions of LE, , and at 100 m height, with a majority scale range of 120 m–4 km in LE, 32 m–2 km in , and 200 m–8 km in . The scales are classified into three scale ranges, the turbulent scale (8–200 m), large‐eddy scale (200 m–2 km), and mesoscale (2–8 km) to evaluate scale‐resolved LE contributed by and . The large‐eddy scale in PBL contributes over 70% of the monthly mean total LE with equal parts (50%) of contributions from and . The monthly temporal variations mainly come from the first two major contributing classified scales in LE, , and . These results confirm the dominant role of the large‐eddy scale in the PBL in the vertical moisture transport from the surface to the PBL, while the mesoscale is shown to contribute an additional ∼20%. This analysis complements published scale‐dependent LE variations, which lack detailed scale‐dependent vertical velocity and moisture information.

 

Nanozymes with intrinsic enzyme-like properties and excellent stability are promising alternatives to natural enzymes. Yet, their low density of active sites and unclear crystal structure have been the major obstacles that impede their progress. Single-atom nanozymes (SAzymes) have emerged as a unique system to mitigate these issues, due to maximal atomic utilization, well-defined electronic and geometric structures, and outstanding catalytic activity distinct from their nanosized counterparts. Furthermore, the homogeneously dispersed active sites and well-defined coordination structures provide rare pathways to shed light on the catalytic mechanisms. In this review, we summarize the latest progress in the rational design and engineering of SAzymes and their applications in biomedicine and biosensing. We then conclude the review with highlights of the remaining challenges and perspectives of this emerging technology. 

Recent high angular resolution ALMA observations have revealed numerous gaps in protoplanetary discs. A popular interpretation has been that planets open them. Most previous investigations of planet gap-opening have concentrated on viscous discs. Here, we carry out 2D (axisymmetric) global simulations of gap opening by a planet in a wind-launching non-ideal MHD disc with consistent thermochemistry. We find a strong concentration of poloidal magnetic flux in the planet-opened gap, where the gas dynamics are magnetically dominated. The magnetic field also drives a fast (nearly sonic) meridional gas circulation in the denser disc regions near the inner and outer edges of the gap, which may be observable through high-resolution molecular line observations. The gap is more ionized than its denser surrounding regions, with a better magnetic field–matter coupling. In particular, it has a much higher abundance of molecular ion HCO+, consistent with ALMA observations of the well-studied AS 209 protoplanetary disc that has prominent gaps and fast meridional motions reaching the local sound speed. Finally, we provide fitting formulae for the ambipolar and Ohmic diffusivities as a function of the disc local density, which can be used for future 3D simulations of planet gap-opening in non-ideal MHD discs where thermochemistry is too computationally expensive to evolve self-consistently with the magneto-hydrodynamics.

 

Abstract The magnitude of water vapor content within the near-storm inflow can either support or deter the storm’s upscale growth and maintenance. However, the heterogeneity of the moisture field near storms remains poorly understood because the operational observation network lacks detail. This observational study illustrates that near-storm inflow water vapor environments are both significantly heterogeneous and different than the far-inflow storm environment. This study also depicts the importance of temporal variation of water vapor mixing ratio (WVMR) to instability during the peak tornadic seasons in the U.S. Southeast and Great Plains regions during the Verification of the Origins of Rotation in Tornadoes Experiment Southeast 2018 (VSE18) campaign and the Targeted Observation by Radar and UAS of Supercells (TORUS) campaign, respectively. VSE18 results suggest that the surface processes control WVMR variation significantly in lower levels, with the highest WVMR mainly located near the surface in inflows in the southeast region. In contrast, TORUS results show more vertically homogeneous WVMR profiles and rather uniform water vapor distribution variation occurring in deep, moist stratified inflows in the Great Plains region. Temporal water vapor variations within 5-min periods could lead to over 1000 J kg −1 CAPE changes in both VSE18 and TORUS, which represent significant potential buoyancy perturbations for storms to intensify or decay. These temporal water vapor and instability evolutions of moving storms remain difficult to capture via radiosondes and fixed in situ or profiling instrumentation, yet may exert a strong impact on storm evolution. This study suggests that improving observations of the variability of near-storm inflow moisture can accurately refine a potential severe weather threat. Significance Statement It has long been recognized that better observations of the planetary boundary layer (PBL) inflow near convective storms are needed to improve severe weather forecasting. The current operational networks essentially do not provide profile measurements of the PBL, except for the sparsely spaced 12-hourly sounding network. More frequent geostationary satellite observations do not provide adequately high vertical resolution in the PBL. This study uses airborne lidar profiler measurements to examine moisture in the inflow region of convective storms in the Great Plains and the southeastern United States during their respective tornadic seasons. Rapid PBL water vapor variations on a ∼5 min time scale can lead to CAPE perturbations exceeding 1000 J kg −1 , representing significant perturbations that could promote storm intensification or decay. Severe thunderstorms may generate high-impact weather phenomena, such as tornadoes, high winds, hail, and heavy rainfall, which have substantial socioeconomic impacts. Ultimately, by contrasting characteristics of the convective storm inflow in the two regions, this study may lead to a more accurate assessment of severe weather threats. 

Biopolymers are an emerging class of novel materials with diverse applications and properties such as superior sustainability and tunability. Here, applications of biopolymers are described in the context of energy storage devices, namely lithium-based batteries, zinc-based batteries, and capacitors. Current demand for energy storage technologies calls for improved energy density, preserved performance overtime, and more sustainable end-of-life behavior. Lithium-based and zinc-based batteries often face anode corrosion from processes such as dendrite formation. Capacitors typically struggle with achieving functional energy density caused by an inability to efficiently charge and discharge. Both classes of energy storage need to be packaged with sustainable materials due to their potential leakages of toxic metals. In this review paper, recent progress in energy applications is described for biocompatible polymers such as silk, keratin, collagen, chitosan, cellulose, and agarose. Fabrication techniques are described for various components of the battery/capacitors including the electrode, electrolyte, and separators with biopolymers. Of these methods, incorporating the porosity found within various biopolymers is commonly used to maximize ion transport in the electrolyte and prevent dendrite formations in lithium-based, zinc-based batteries, and capacitors. Overall, integrating biopolymers in energy storage solutions poses a promising alternative that can theoretically match traditional energy sources while eliminating harmful consequences to the environment.